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ABSTRACT:?Objective?To improve the property of the paper cultural relic and archive including waterproof, acidproof, anti-aging, etc.?Methods?Put the samples into JRP¡¯s coating equipment, then the Nano protective?film layer is polymerized on the surface of samples under conditions of vacuum, temperature, electric field, magenetic field, and chemical raw material.By the tests of chromatic value before and after aging, water contact angle, fold resistant, tensile strength, and immersion in seawater, to evaluate respectively samples¡¯ properties of waterproof, acidproof, anti-aging, anti-tear, etc. Meanwhile by using SEM to test and analysize the Nano protective polymerized film.?Results?the chromatic aberration of Coated paper is small under the following condintions: before and after hygrothermal aging, before and after ultraviolet aging, before and after acid rain aging.?The average value of water contact angle of front and back side of the coated Chinese art paper is over?90¡ã, but the water contact angle value of un-coating paper is 0, in the state of complete wetting.?SEM photos show that the macro-size of paper fiber is no changed, and no jams between the holes of fiber. The test of fold resistant shows that the longitudinal folding strength of coated paper can be improved slightly. The test of tensile strength shows that the crosswise tensile strength of coated paper is apparently much higher than the original paper. The tests of acid etching and seawater immersion show that the coated ones are with better performance of anti-acid etching and anti-seawater corrosion than un-coated ones.?Coating makes the paper with good waterproof and hydrophobic functions. Coating improves the folding strength and tensile strength of paper. The coating film is with acid proofing and anti-seawater corrosion function, so it protects the substrate.
Key Words: Vacuum Nano Coating, Polymer, Water Contact Angle, Cultural relics preservation, Archives preservation, Cultural relics waterproof, hydrophobic, water repellent
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±í1Ö½ºÍ±í²ãµÄ¶ÆĤֽ±¥ºÍ¶ÈÖµºÍÉ«²î²âÊÔ
Tab.1Chromatic value and aberration test of coated paper and un-coated paper
±¥ºÍ¶ÈÖµ | Ö½£¨75x150mm£© | ±í²ãµÄ¶ÆĤֽ£¨75x150mm£© |
L* | 63.0 | 63.2 |
a* | 4.4 | 4.5 |
b* | 13.1 | 13.3 |
¦¤L* | 0.2 | |
¦¤a* | 0.1 | |
¦¤b* | 0.2 | |
¦¤E | 0.3 |
±í2?ËáÓêµÄΣº¦Ë¥ÀϺóµÄÖ½ºÍ±í²ãµÄ¶ÆĤֽ±¥ºÍ¶ÈºÍÉ«Îó²î¼ì²âʵ¼ÊЧ¹û
Tab.2 Chromatic value and aberration test of coated paper and un-coated paper after acid rain aging
±¥ºÍ¶È£¬Æ«É« | Ö½£¨150x15mm£© | ±í²ãµÄ¶ÆĤֽ£¨150x15mm£© |
L* | 69.8 | 69.8 |
a* | 15.4 | 16.2 |
b* | 23.7 | 22.6 |
¦¤L* | 0.2 | -0.3 |
¦¤a* | 1.6 | 2.4 |
¦¤b* | -0.7 | -1.6 |
¦¤E | 1.7 | 2.9 |
±í3?º®ÊªË¥ÀϺóµÄÖ½ºÍ±í²ãµÄ¶ÆĤֽ±¥ºÍ¶ÈÖµºÍÉ«²î²âÊÔ
Tab.3 Chromatic value and aberration test of coated paper and un-coated paper after hygrothermal aging
±¥ºÍ¶È£¬Æ«É« | Ö½£¨150x15mm£© | ±í²ãµÄ¶ÆĤֽ£¨150x15mm£© | |
L* | 61.9 | 63.6 | |
a* | 4.8 | 4.8 | |
b* | 13.7 | 13.7 | |
¦¤L* | -1.1 | 0.1 | |
¦¤a* | 0.1 | 0.1 | |
¦¤b* | 0.4 | 0.1 | |
¦¤E | 1.1 | 0.1 | |
±í4×ÏÍâ¹âË¥ÀϺóµÄÖ½ºÍ±í²ãµÄ¶ÆĤֽ±¥ºÍ¶ÈÖµºÍÉ«²î²âÊÔ
Tab.4 Chromatic value and aberration test of coated paper and un-coated paper after ultraviolet aging
±¥ºÍ¶È£¬Æ«É« | Ö½£¨450x450mm£© | ±í²ãµÄ¶ÆĤֽ£¨450x450mm£© | ||
L* | 68.0 | 66.0 | ||
a* | 3.6 | 3.7 | ||
b* | 13.9 | 14.7 | ||
¦¤L* | 5.0 | 2.4 | ||
¦¤a* | -0.8 | -0.6 | ||
¦¤b* | 0.8 | 1.6 | ||
¦¤E | 5.1 | 2.9 |
3.2?´òÓ¡Ö½Õűí²ãµÄ¶ÆĤǰºó×óÓÒSEMÆÊÎö
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±í5?ÔÉúÐûÖ½±íÃæÕÅÁ¦¼ì²âʵ¼ÊЧ¹û
Tab.5 water contact angle of original Chinese art paper
¼ì²âƵ´Î | ÔÉúÐûÖ½ÕýÁ³±íÃæÕÅÁ¦ | ÔÉúÐûÖ½±³Ãæ±íÃæÕÅÁ¦ | ||
???????????¦È/¡ã | ????????????¦È/¡ã | |||
1 | ?????????0 | ????????????0 | ||
2 | ?????????0 | ????????????0 | ||
3 | ?????????0 | ????????????0 | ||
Average value | ?????????0 | ????????????0 |
±í6 JRP±í²ãµÄ¶ÆĤÉúÐûÖ½±íÃæÕÅÁ¦¼ì²âʵ¼ÊЧ¹û
Tab.6 water contact angle test of JRP coated Chinese art paper
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????????????¦È/¡ã | ?????????????¦È/¡ã | |||
1 | ?????????120.80 | ??????????116.00 | ||
2 | ?????????117.00 | ??????????117.00 | ||
3 | ?????????122.00 | ??????????116.64 | ||
Average value | ?????????119.93 | ??????????116.55 |
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Tab.7 Folding strength test of paper
ÄÍÕÛ¶È/´Î | Ô´òÓ¡Ö½ÕÅ | ±í²ãµÄ¶ÆĤ´òÓ¡Ö½ÕÅ | ||
ºá×Å | ÊúÏò | ºá×Å | ÊúÏò | |
ƽÐÐÃæÑùÒ» | 8 | 1 | 8 | 2 |
ƽÐÐÃæÑù¶þ | 8 | 1 | 7 | 2 |
ƽÐÐÃæÑùÈý | 9 | 1 | 10 | 2 |
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Data processing
ºá×Å | ÊúÏò | ||
Ô´òÓ¡Ö½ÕÅ | Ö¸±êÖµ/´Î | 8.3 | 1 |
Ïà¶ÔÐÔ±ê×¼Îó²î?/??% | 0.6 | 0 | |
±í²ãµÄ¶ÆĤֽ | Ö¸±êÖµ/´Î | 8.3 | 2.0 |
Ïà¶ÔÐÔ±ê×¼Îó²î?/??% | 1.5 | 0.0 |
3.5?´òÓ¡Ö½ÕÅ¿¹ÀÇ¿¶ÈÆÊÎö
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±í8?´òÓ¡Ö½Õź®ÊªË¥ÀϺó¿¹ÀÇ¿¶È¼ì²âʵ¼ÊЧ¹û
Tab.8 Tensile strength test of paper after hygrothermal aging
Ô´òÓ¡Ö½ÕÅ | ±í²ãµÄ¶ÆĤ´òÓ¡Ö½ÕÅ | |||
¿¹ÀÇ¿¶È?/ mN | ºá×Å | ÊúÏò | ºá×Å | ÊúÏò |
ƽÐÐÃæÑùÒ» | 10816.51 | 6233.274 | 13422.0 | 7052.4 |
ƽÐÐÃæÑù¶þ | 11463.97 | 5870.304 | 11653.3 | 6121.4 |
ƽÐÐÃæÑùÈý | 10490.81 | 6686.496 | 12269.4 | 5654.5 |
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Data processing
ºá×Å | ÊúÏò | ||
Ô´òÓ¡Ö½ÕÅ | ¾ùÖµ?/ mN | 10923.8 | 6263.4 |
Ïà¶ÔÐÔ±ê×¼Îó²î?/ % | 4.5 | 6.5 | |
±í²ãµÄ¶ÆĤ´òÓ¡Ö½ÕÅ | ¾ùÖµ?/ mN | 12448.2 | 6276.1 |
Ïà¶ÔÐÔ±ê×¼Îó²î?/ % | 7.2 | 11.3 | |
±í²ãµÄ¶ÆĤ º®ÊªË¥ÀÏÇ°ºó×óÓÒ¿¹ÀÇ¿¶ÈÌá¸ß?/ % | 32.3 | 14.0 |
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